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Bowl Fresh Automatic Bowl Cleaner-12/04/2014-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaBowl Fresh In-Tank Toilet Bowl Cleaners help eliminate inorganic soil; uric acid salts and prevents stains caused by hard water. Borax powered formula cleans, deodorizes and leaves bowl water with a blue tint after each flush. Made in the USA and is safe for plumbing and septic systems.
Purpose of product.
Usage: Toilet/urinal care productStructure such as solid, liquid, aerosol etc.
Form: solidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 20244044 Park Avenue
Saint Louis MO 63110
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 007757-82-6 -- -- -- -- -- 001330-43-4 -- 20.0-30.0 -- -- -- -- 068081-81-2 -- 10.0-20.0 -- -- -- -- 007647-14-5 -- -- -- -- -- 009004-32-4 -- -- -- -- -- 009004-62-0 -- -- -- -- -- 003844-45-9 -- -- -- -- -- 007732-18-5 -- -- -- -- -- 068140-00-1 -- 1.0-5.0 -- -- -- -- 010043-01-3 -- 1.0-5.0 -- -- -- -- 000064-02-8 -- -- -- -- -- 025322-68-3 -- -- -- -- -- 000077-92-9 -- Xi -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Sodium sulfate
007757-82-6
231-820-9-- No -- P262 -- No No Sodium tetraborate anhydrous
001330-43-4
215-540-420.0-30.0 No H360, H319 -- Yes No C10-16 Alkylbenzene Sulfonic Acid
068081-81-2
268-356-110.0-20.0 No -- -- -- No No Sodium chloride
007647-14-5
231-598-3-- No -- -- -- No No Sodium Carboxymethyl Cellulose
009004-32-4
--- No -- -- -- Yes No Hydroxyethyl cellulose
009004-62-0
--- No -- -- -- Yes No Acid Blue 9
003844-45-9
223-339-8-- No -- -- -- No No Water
007732-18-5
231-791-2-- No -- -- -- No No Cocamide MEA
068140-00-1
268-770-21.0-5.0 No -- -- -- No No Aluminum sulfate anhydrous
010043-01-3
233-135-01.0-5.0 No H226 P210, P243, P403+P235 No No Tetrasodium EDTA
000064-02-8
200-573-9-- No H332, H302, H318 -- No No Glycols, polyethylene
025322-68-3
500-038-2-- No -- -- -- No No Citric acid
000077-92-9
201-069-1-- No H319 P264, P280, P305, P351, P338, P337, P313 No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H226 : Flammable liquid and vapourH302 : Harmful if swallowedH318 : Causes serious eye damageH319 : Causes serious eye irritationH332 : Harmful if inhaledH360 : May damage fertility or the unborn child
- P210 : Keep away from heat/sparks/open flames/hot surfacesP243 : Take precautionary measures against static dischargeP262 : Do not get in eyes, on skin, or on clothingP264 : Wash … thoroughly after handlingP280 : Wear protective gloves/protective clothing/eye protection/face protectionP305 : IF IN EYES:P313 : Get medical advice/attentionP337 : If eye irritation persists:P338 : Remove contact lenses if present and easy to do. continue rinsingP351 : Rinse continuously with water for several minutes
- GHS02 : FlammableGHS05 : CorrosiveGHS07 : IrritantGHS08 : Health Hazard
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :December 04, 2014 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING1 0 0 -
V.O.C Information
Volatile Organic Compounds %/Wt. With Solvent : 0
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SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
CAUTION: Harmful if swallowed. Eye irritant. Contains borax, anionic and nonionic surfactants. Do not use or mix with other household chemicals. Keep out of reach of children.
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Acute health effects
From MSDS:
Hazards Identification.
Emergency Overview: Harmful if swallowed. Dust or vapors may cause eye and respiratory tract irritation. Repeated or prolonged contact may cause skin irritation or allergic skin reactions. Repeated inhalation of dusts could cause respiratory sensitization reactions.
Potential Health Effects
Primary Route(s) of Exposure: Ingestion, Eye Contact, Inhalation, Skin Contact.
Eye Contact: Dust or vapors may cause irritation.
Skin Contact: Repeated or prolonged contact may cause skin irritation.
Inhalation: Dust or vapors may cause irritation.
Ingestion: May be harmful if swallowed.
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Chronic health effects
From MSDS:
Repeated inhalation exposure to dusts may cause sensitization in susceptible individuals. Symptoms could include difficulty in breathing, shortness of breath, asthmatic attack, skin rashes, and severe eye irritation. -
Carcinogenicity
No data available on the formulated product.
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Handling information
Store in a dry area at room temperature. Do not generate dust or exposure to ignition source. Keep away from heat, sparks, and flame.
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Disposal information
Dispose of material, liners, and containers in accordance with all applicable federal, state, and local environmental regulations.
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California Prop. 65 Warning
None of the ingredients are listed.
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First Aid
Eye Contact: Immediately flush eyes with a directed stream of water for at least 15 minutes, forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. Remove contact lenses, if present, after the first five minutes and continue rinsing the eye. Call a physician or poison control center immediately.
Skin Contact: Immediately flush skin with plenty of water while removing contaminated clothing and shoes. Wash clothing before reuse. If irritation occurs, get medical attention.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
Ingestion: Do not give anything by mouth to an unconscious person. Call poison control center or doctor immediately for treatment advice. Have person rinse the mouth with water. If able to swallow, have the person sip a glass of water. Do not induce vomiting unless told to do so by a poison control center or doctor.
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